"Antimony(V) Fluoride" in Encyclopedia of Reagents for Organic Synthesis (Ed: L. Paquette) 2004, J. Wiley & Sons, New York. Fluorine's chemistry includes inorganic compounds formed with hydrogen, metals, nonmetals, and even noble gases; as well as a diverse set of organic compounds. As well as some industrial applications, it is used as a reagent in inorganic and organofluorine chemistry. This effect is illustrated by the oxidation of oxygen:[9]. Antimony pentafluoride is prepared by treating antimony pentachloride with excess anhydrous hydrogen fluoride. Niobium(V) fluoride, also known as niobium pentafluoride, is the inorganic compound with the formula NbF5. Would you like Wikipedia to always look as professional and up-to-date? This colourless, viscous liquid is a valuable Lewis acid and a component of the superacid fluoroantimonic acid, the strongest known acid formed when mixing liquid HF with liquid SbF 5 in a 2:1 ratio. Sabina C. Grund, Kunibert Hanusch, Hans J. Breunig, Hans Uwe Wolf "Antimony and Antimony Compounds" in Ullmann's Encyclopedia of Industrial Chemistry 2006, Wiley-VCH, Weinheim. Antimony pentafluorideis the inorganic compoundwith the formula SbF5. Vol. The material adopts a more complicated structure in the liquid and solid states. Edwards, A. J.; Taylor, P. "Crystal structure of Antimony Pentafluoride" Journal of the Chemical Society, Chemical Communications 1971, pp. Edited by G. Brauer, Academic Press, 1963, NY. The solid consists of tetramers [NbF5]4. Over- exposure by any route can cause bloody stools, slow pulse rate, low blood pressure, coma, convulsions, and … We have created a browser extension. This colourless, viscous liquid is a valuable Lewis acidand a component of the superacidfluoroantimonic acid, the strongest known acid. The most well studied example is the highly chlorinated derivative H(CHB11Cl11). Shamir, J.; Binenboym, J. Molecules containing fluorine may also exhibit hydrogen bonding. Perchloryl fluoride is a reactive gas with the chemical formula ClO3F. The Sb-F bonds are 2.02 Å within the eight-membered Sb4… Antimony pentafluoride is the inorganic compound with the formula SbF5. The Species In Solution (A) Has Been Identified As The Salt C8H12X2 Where X Is An Hexahaloantimonate Anion. BiF5 is a polymer. SbF5 is a strong Lewis acid, exceptionally so toward sources of F− to give the very stable anion [SbF6]−, called hexafluoroantimonate. The acidity of H(CHB11Cl11) was found to vastly exceed that of triflic acid, CF3SO3H, and bistriflimide, (CF3SO2)2NH, compounds previously regarded as the strongest isolable acids. It is the acid fluoride of perchloric acid. With other atoms, fluorine forms either polar covalent bonds or ionic bonds. It is a colorless liquid which reacts readily with water. The crystalline material is a tetramer, meaning that it has the formula [SbF4(μ-F)]4. Arsenic trifluoride is a chemical compound of arsenic and fluorine with the chemical formula AsF3. It will enhance any encyclopedic page you visit with the magic of the WIKI 2 technology. This strong Brønsted acid features a non-coordinating anion, hexafluorophosphate. Holleman, A. F.; Wiberg, E. "Inorganic Chemistry" Academic Press: San Diego, 2001. I use WIKI 2 every day and almost forgot how the original Wikipedia looks like. It is notable for its Lewis acidity and its ability to react with almost all known compounds. It is exceptionally corrosive and can only be stored in containers lined with PTFE (Teflon). In the gas phase, SbF5 adopts a trigonal bipyramidal structure of D3h point group symmetry (see picture). Antimony pentafluoride is the inorganic compound with the formula Sb F 5. The source code for the WIKI 2 extension is being checked by specialists of the Mozilla Foundation, Google, and Apple. Holleman, A. F.; Wiberg, E. "Inorganic Chemistry" Academic Press: San Diego, 2001. [4], Antimony pentafluoride is prepared by the reaction of antimony pentachloride with anhydrous hydrogen fluoride:[5], It can also be prepared from antimony trifluoride and fluorine. Setup: There are a total of 40 valance electrons (five from Sb atom and seven from each F atoms). Congratulations on this excellent venture… what a great idea! It is formed from the reaction of hydrogen fluoride with phosphorus pentafluoride. It will enhance any encyclopedic page you visit with the magic of the WIKI 2 technology. It appears as a white solid. Sometimes called Swarts' reagent, is one of two principal fluorides of antimony, the other being SbF5. Edited by G. Brauer, Academic Press, 1963, NY. It is notable for its Lewis acidity and its ability to react with almost all known compounds. Antimony trifluoride is the inorganic compound with the formula SbF3. Olah, G. A.; Prakash, G. K. S.; Wang, Q.; Li, X.-y.

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